WO/2009/004843 is referenced by 2 patents.

(EN) A catalyst for the aromatization of lower hydrocarbons which is improved in the activity life stability in terms of methane conversion, benzene formation rate, naphthalene formation rate and BTX formation rate (total formation rate of benzene, toluene, and xylene) and brings about an increase in the yield of useful aromatic compounds such as benzene and toluene, comprising a metallosilicate and molybdenum and silver which are supported on the metallosilicate. It is preferable that the catalyst be prepared by modifying a zeolite consisting of a metallosilicate with a silane compound which has a molecular diameter larger than the pore diameter of the zeolite and bears both an amino group selectively reactive with a Brønsted acid site of the zeolite and a linear hydrocarbon group and then making molybdenum and silver supported on the modified zeolite. In producing aromatic compounds, the catalyst enables the reaction of a reaction gas containing both lower hydrocarbons and carbon dioxide.(JA)  メタン転換率、ベンゼン生成速度、ナフタレン生成速度及びBTX生成速度(ベンゼンとトルエンとキシレンの合計生成速度)の活性寿命安定性を向上させてベンゼン、トルエン等の有用な芳香族化合物の生成量を増大させるための低級炭化水素の芳香族化触媒は担体であるメタロシリケートにモリブデンと銀を担持してなる。前記芳香族化触媒はメタロシリケートからなるゼオライトを前記ゼオライトの細孔口径よりも大きな分子径であると共に、前記ゼオライトのブレーンステッド酸点に選択的に反応するアミノ基と直鎖炭化水素基を有するシラン化合物で修飾した後にモリブデンと銀を担持して得るとなおよい。これらの芳香族化触媒は、芳香族化合物の製造方法を製造するにあたり、低級炭化水素と炭酸ガスとを含む反応ガスを反応させる。

Title
(Ja) 低級炭化水素の芳香族化触媒、芳香族化合物の製造方法
(En) Catalyst for aromatization of lower hydrocarbons and process for production of aromatic compounds
Application Number
PCT/JP2008/056117
Publication Number
2009/004843
Application Date
March 28, 2008
Publication Date
January 8, 2009
Inventor
Sugiyama Yoshio
Yamamoto Yo
Hatagishi Takuya
Ogawa Yuji
Yamada Tomohiro
Yamada Shinichi
Agent
HASHIMOTO Takeshi
Assignee
Sugiyama Yoshio
Yamamoto Yo
Hatagishi Takuya
Ogawa Yuji
Yamada Tomohiro
Yamada Shinichi
Meidensha Corporation
IPC
C07B 61/00
C07C 02/76
C07C 15/08
C07C 15/06
C07C 15/04
B01J 37/08
B01J 29/48
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