08779067 is referenced by 1 patents and cites 244 patents.

This invention relates to a co-oligomer having an Mn of 300 to 30,000 g/mol comprising 10 to 90 mol % propylene and 10 to 90 mol % of ethylene, wherein the oligomer has at least X % allyl chain ends, where: 1) X=(−0.94 (mole % ethylene incorporated)+100), when 10 to 60 mole % ethylene is present in the co-oligomer, and 2) X=45, when greater than 60 and less than 70 mole % ethylene is present in the co-oligomer, and 3) X=(1.83*(mole % ethylene incorporated)−83), when 70 to 90 mole % ethylene is present in the co-oligomer. This invention also relates to a homo-oligomer, comprising propylene, wherein the oligomer has: at least 93% allyl chain ends, an Mn of about 500 to about 20,000 g/mol, an isobutyl chain end to allylic vinyl group ratio of 0.8:1 to 1.2:1.0, and less than 100 ppm aluminum. This invention also relates to a process of making homo-oligomer, comprising propylene, wherein the productivity is greater than 4500 g/mmol Hf (or Zr)/hour.

Title
High vinyl terminated propylene based oligomers
Application Number
13/670108
Publication Number
8779067 (B2)
Application Date
November 6, 2012
Publication Date
July 15, 2014
Inventor
Andrew G Narvaez Jr
Pasadena
TX, US
Donna J Crowther
Seabrook
TX, US
Patrick Brant
Seabrook
TX, US
Agent
Catherine L Bell
Kevin M Faulkner
Assignee
ExxonMobil Chemical Patents
TX, US
IPC
C08F 4/76
C08F 4/64
C08F 210/16
View Original Source