03998786 is referenced by 74 patents and cites 6 patents.

A process for preparing substantially completely cyclized aromatic polyimides, either monomeric, oligomeric or polymeric, is provided. The process involved the reaction of a mixture of at least one tetracarboxylic acid dianhydride and at least one aromatic diamine in at least one aromatic phenol, preferably cresols, in the presence of an organic azeotroping agent such as a cyclic hydrocarbon, preferably benzene, until substantially all of the water of reaction is eliminated. Other monomers, e.g., a monoamine or an .alpha.,.beta.-carboxylic acid monoanhydride can be added to the mixture so as to provide reactive end groups, preferably olefinically terminated, which will enable the polyimide to cure by coupling together by addition or condensation thereby increasing molecular weight with little or no by-product. After the water is removed, it is preferred that the azeotroping agent be removed and then the polyimide increased in molecular weight by heating in the aromatic phenol.

The polymer can then be isolated by concentration or precipitation as a powder, or the polymer in solution can be used to prepare coatings on various substrates.

Process for preparing aromatic polyimides, polyimides prepared thereby
Application Number
Publication Number
Application Date
May 25, 1973
Publication Date
December 21, 1976
Gaetano Francis D Alelio
South Bend
University of Notre Dame du Lac
C08G 73/12
C08G 73/10
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