0576970-A1 is referenced by 143 patents and cites 4 patents.

A very active catalyst system for the polymerisation or copolymerisation of olefins consists of a co-catalyst, preferably an aluminoxane or a supported aluminoxane, and a metallocene of the formula I in which, in the preferred form, M denotes Zr or Hf, R and R denote halogen or alkyl, R denotes alkyl, R to R denote alkyl or hydrogen and R denotes a (substituted) alkylene or heteroatom bridge. The metallocenes, in particular the zirkonocenes, produce polymers of very high molecular weight in the industrially particularly interesting temperature range between 50 and 80 DEG C if the catalyst activities are high, and polymers of very high molecular weight, very high stereotacticity and high melting point in the case of prochiral monomers. Moreover, using supported catalyst systems, reactor coatings are avoided.

Title
Metallocenes with arylsubstituted indenyl-derivatives as ligands, process for their preparation and their use as catalysts.
Application Number
EP19930109966 19930622
Publication Number
0576970 (A1)
Application Date
June 22, 1993
Publication Date
January 5, 1994
Inventor
Rohrmann Juergen Dr
DE
Winter Andreas Dr
DE
Spaleck Walter Dr
DE
Bachmann Bernd Dr
DE
Kueber Frank Dr
DE
Assignee
Hoechst
DE
IPC
C08F 10/00
C07F 17/00
C08F 297/00
C08F 10/00
C08F 04/00
C07F 17/00
C07C 49/00
C07C 45/00
C07C 17/00
C07F 07/00
C08F 297/08
C08F 10/00
C08F 04/6592
C08F 04/64
C08F 04/60
C08F 04/42
C08F 04/16
C07F 17/00
C07C 49/67
C07C 45/46
C07C 17/14
C07F 07/00
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